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What is the chemical structure of 4,4 '-diiodo-1,1': 4 ', 1' -terphenyl?
4,4 '-diiodine-1,1': 4 ', 1' -biphenyl has a unique chemical structure. This compound belongs to the class of triphenyls, which are formed by connecting three benzene rings through specific bonds. The structure of triphenyl, like the backbone of a building, lays the foundation for its pattern.
On this structure, at the position of 4 and 4 ', one iodine atom is connected. Iodine atoms have a large atomic weight and have unique electron clouds and spatial resistance. Its connection to benzene rings, such as pearl mosaics, has a significant impact on the physical and chemical properties of compounds.
From the perspective of electronic effects, the electronegativity of iodine is different from that of benzene cyclic carbon, which makes the distribution of benzene cyclic electron clouds deviate, affecting its chemical reaction activity, or increasing or decreasing, depending on the reaction situation. In terms of steric hindrance, iodine atoms are large in size, creating a special spatial environment around molecules, which has an impact on intermolecular interactions, crystal morphology, solubility, etc.
In this way, 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl, with its unique chemical structure, has great potential in many fields such as materials science and organic synthesis. It is waiting for the world to explore in depth and tap its endless value.
What are the main uses of 4,4 '-diiodo-1,1': 4 ', 1' -terphenyl?
4,4 '-diiodine-1,1': 4 ', 1' -terphenyl is also an organic compound. It has a wide range of uses and is often used as a key intermediate in the field of organic synthesis. Due to its unique molecular structure, it can add more functional groups through chemical reactions, and then prepare various organic materials with special properties.
In the field of materials science, the use of this compound is particularly important. First, in the field of optoelectronic materials, it can exhibit excellent optoelectronic properties after modification, such as being used as a light-emitting layer material for organic Light Emitting Diodes (OLEDs) to help it emit light of specific colors and improve luminous efficiency and stability. Second, in the field of semiconductor materials, it may be reasonably designed to give it a suitable energy band structure, which can be used as the active layer material of organic field effect transistors (OFETs), which affects the charge transport and improves the electrical properties of the device.
Furthermore, in the field of supramolecular chemistry, the existence of 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl-iodine atoms and benzene ring structures can self-assemble with other molecules to form an ordered supramolecular structure through non-covalent interactions, such as halogen bonds, π-π stacking, etc. This supramolecular structure may show unique functions and application potential in molecular recognition, catalysis, and simulation of biological systems.
In addition, in academic research, this compound is also an ideal model for exploring the relationship between molecular structure and properties. Researchers can deeply study the effects of molecular electron cloud distribution, steric hindrance effect and other factors on the physical and chemical properties of compounds by changing their substituents and adjusting molecular configurations, providing theoretical basis for the design and synthesis of new compounds.
What are the physical properties of 4,4 '-diiodo-1,1': 4 ', 1' -terphenyl?
4,4 '-Diiodine-1,1': 4 ', 1' -terphenyl, is one of the organic compounds. It has several physical properties, which are hereby described by you.
Looking at its properties, at room temperature, this substance is mostly in a solid state, and its appearance may be white to light yellow powder. This is due to the orderly arrangement of its molecular structure, and the intermolecular forces make it exist in a solid state.
On the melting point, 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl has a specific melting point value. For the melting point, the critical temperature at which the substance changes from a solid state to a liquid state is also. The melting point of this compound is generally within a certain range due to different or slightly changed conditions for accurate determination. This property is related to the strength of its intermolecular binding force, which can provide a key basis for substance identification and purification.
As for solubility, 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl shows different solubility in organic solvents. Common organic solvents such as toluene and xylene of aromatic hydrocarbons have a certain solubility. This is because of the principle of "similarity and miscibility", the molecular structure of the compound is in agreement with the structure of aromatic hydrocarbon solvents, and the intermolecular force can promote its dissolution. However, in solvents with strong polarity such as water, their solubility is very small, because the molecular polarity difference between the two is too large, the interaction is difficult to overcome the intermolecular forces, resulting in difficulty in dissolution.
Furthermore, the density of 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl is also one of its physical properties. Density reflects the mass of a substance per unit volume. This value is closely related to the molecular composition and crystal structure of the compound. In specific application scenarios such as material preparation and separation processes, density considerations are indispensable.
In summary, the physical properties of 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl, such as appearance, melting point, solubility, and density, are of great significance for their applications in chemical synthesis, materials science, and many other fields.
What are the synthesis methods of 4,4 '-diiodo-1,1': 4 ', 1' -terphenyl?
The synthesis methods of 4,4 '-diiodo- 1,1': 4 ', 1' -terphenyl are many different. The following are the common ones.
One is the Suzuki coupling reaction method. Take iodine-containing benzene derivatives, react with phenylboronic acid compounds in the presence of palladium catalyst, base and suitable solvent. The reaction conditions are mild and the selectivity is quite good. The palladium catalyst is often selected as tetrakis (triphenylphosphine) palladium, etc., and the base is potassium carbonate, sodium carbonate, etc. Solvents such as toluene, dioxane, etc. can be used. The reaction mechanism is that the palladium catalyst is first oxidized with halogenated aromatics to form a palladium (ⅱ) complex, then metallized with phenylboronic acid, and finally eliminated by reduction to form the target product.
The second is the Ullmann reaction method. Halogenated aromatics are used as raw materials and react under the action of copper catalysts and bases. This reaction has a long history, but it requires a higher temperature and slightly higher requirements for reaction equipment. Copper catalysts are commonly used for copper oxide, cuprous iodide, etc., and potassium carbonate is selected for the base. In the reaction, the copper catalyst promotes the formation of aryl copper intermediates from halogenated aromatics, and then couples with another halogenated aromatic hydrocarbon to form terphenyl products.
The third is the Stille coupling reaction method. Organotin reagents are used to react with halogenated aromatics under the action of palladium catalysts. Organotin reagents have high activity and good reaction efficiency. Palladium catalysts such as bis (triphenylphosphine) palladium dichloride are commonly used. However, organotin reagents are highly toxic and need to be used with caution. During the reaction, the palladium catalyst is first oxidized with halogenated aromatics, and then transmetallized with organotin reagents, and finally reduced and eliminated to obtain the target product 4,4 '-diiodine-1,1': 4 ', 1' -terphenyl.
What is the price range of 4,4 '-diiodo-1,1': 4 ', 1' -terphenyl in the market?
4,4 '-diiodine-1,1': 4 ', 1' -terphenyl in the market, what is the price? This question is quite tricky, because the market situation is complex and changeable, and the price range is difficult to determine. However, according to past transactions and market conditions, the price may vary depending on quality, purity, supply and demand. If it is a high-purity product, and the market demand is strong, its price may be high; conversely, if the quality is flat and the supply is more than the demand, the price may be slightly lower.
If you taste this kind of product, if the purity is high, the price per gram can reach tens of gold, or even hundreds of gold; if the purity is slightly lower, the price may drop to several gold per gram. However, this is only an approximate number, and the actual price depends on the specific business, purchase volume and market conditions. If the buyer wants to know the exact price, he should consult the chemical raw material supplier or explore the chemical trading platform to get a near-real price. In the sea of market trade, prices are like waves and change from time to time, so if you want to get an accurate price, you must take real-time feelings as the criterion.